Tetraarylethylene having two nitroxide groups: redox-switching of through-bond magnetic interaction by conformation change.

نویسندگان

  • Akihiro Ito
  • Yoshiaki Nakano
  • Tatsuhisa Kato
  • Kazuyoshi Tanaka
چکیده

Reversible redox-switching of through-bond magnetic interaction has been achieved by conformation change of the tetraarylethylene moiety upon redox input: intramolecular magnetic interaction between two nitroxide groups is dead after oxidation, whereas it was alive before.

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عنوان ژورنال:
  • Chemical communications

دوره 3  شماره 

صفحات  -

تاریخ انتشار 2005